SAFETY DATA SHEET Vulcan P RFU (HSE No.:7437) 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product name
PelGar International Ltd Unit 13, Newman Lane Industrial Estate, Newman Lane, Alton, Hampshire GU34 2QR
Telephone Product code 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components
Permethrin 0.25% CAS 52645-53-1 Xn; R20/22 R43 N; R50/53 Piperonyl Butoxide 0.75% CAS 51-03-6 N; R51/53 Tetramethrin 0.125% CAS 7696-12-0 N; R50/53 Petroleum Distillates Hydrotreated Light Oil 90-100%
3. HAZARDS IDENTIFICATION Most important hazards
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed.
Specific hazards
Product can accumulate static charges which can cause an incendiary electrical discharge. Material can form flammable mixtures or can burn only if heated to temperatures at or above the flash point.
4. FIRST AID MEASURES Skin contact
Remove contaminated clothing Wash off immediately with soap and plenty of water. If irritation persists obtain medical attention. Contaminated clothing should be washed and dried before re-use
Eye contact
Rinse immediately with plenty of water for at least 15 minutes. If irritation persists obtain medical attention
Inhalation
Inhalation of mist or spray, may cause irritation of the respiratory system. Move to fresh air. Obtain medical advice immediately.
Ingestion
Do not induce vomiting. If conscious give a small amount of milk or water to drink and obtain medical attention. Show the container label or this safety data sheet to the doctor
General advice
In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
5. FIRE-FIGHTING MEASURES Suitable extinguishing
Keep fire exposed containers cool by spraying with water if exposed to fire. Fight surrounding
fire with foam, dry chemical, water spray or mist.
Extinguishing media which must not be used for safety reasons Specific hazards
Combustible material. Fire may cause toxic fumes (oxides of carbon) to evolve. Avoid spraying water directly into storage containers due to danger of boilover.
Vulcan P RFU Special protective
In the event of fire, wear a self-contained breathing apparatus and a chemical protection suit,
equipment for firefighters 6. ACCIDENTAL RELEASE MEASURES Personal precautions
Wear suitable protective clothing, gloves and eye/face protection.See section 8. Keep public away.
Environmental
Prevent further leakage or spillage if safe to do so. Contain or absorb leaking liquid with earth or
precautions
sand. Prevent liquid entering watercourses, sewers or basements. Prevent product from entering drains. If substance has entered a watercourse or sewer or contaminated soil or vegetation, inform the appropriate authority.
Methods for cleaning up
Soak up with inert absorbent material. Transfer to a suitably labelled container. Subsequently, wash the contaminated area with water, or detergent and water, taking care to prevent the washings from entering surface water drains. For large spills, recover by pumping (use an explosion proof or hand pump).
7. HANDLING AND STORAGE Handling
Material will accumulate static charge, which may cause an electrical spark (ignition source). Take precautionary measures against static discharges Do not apply in the presence of naked flames, hot surfaces or unprotected electrical equipment. Ensure all equipment is electrically grounded before beginning transfer operations Container remains hazardous when empty. Continue to observe all precautions. The product is flammable but not readily ignited. Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Keep away from open flames, hot surfaces and sources of ignition - No smoking. If splashing is likely to occur wear approved eye protection. If spray mists are likely, wear a suitable approved respirator. If skin contact is likely to occur wear rubber gloves and suitable impervious protective clothing. Use in a well ventilated area where possible. Always use good personal hygiene procedures when handling chemicals. Do not smoke eat or drink while handling this product. Wash hands, face and exposed skin after using, and before eating, drinking or smoking. Read the label before use. Keep product and empty container away from heat and sources of ignition.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food and animal feedstuffs Store in accordance with Health and Safety Executive's Guidance Note HSG71 Keep away from oxidising agents Keep away from sources of ignition.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limit(s)
Petroleum Distillates Hydrotreated Light Oil TWA(ppm):300
Engineering measures
The use of mechanical (explosion proof) dilution ventilation is recommended whenever this product is used in a confined space.
Respiratory protection
Suitable approved respirator if exposed to spray mists
Hand protection Eye protection
If splashes are likely to occur, wear goggles
Skin and body protection 9. PHYSICAL AND CHEMICAL PROPERTIES Description Boiling point/range Vulcan P RFU Flash point Explosive properties Vapour pressure Relative density Water solubility Viscosity Vapour density Melting point/range Autoignition temperature 10. STABILITY AND REACTIVITY Stability Conditions to avoid Materials to avoid Hazardous decomposition products 11. TOXICOLOGICAL INFORMATION Acute toxicity
ORL RAT LD50 > 2000 mg/kg (calculated) DERMAL RAT LD50 > 4000mg/kg (calculated) Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Vapour concentrations above recommended exposure levels might be irritating to eyes and the respiratory tract.
Sensitisation
May cause sensitisation of susceptible persons by skin contact.
Repeated or prolonged
Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitisation
exposure mutagenic effects carcinogenic effects 12. ECOLOGICAL INFORMATION Ecotoxicity effects
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Further Information
This product must not enter water discharge system. Inform appropriate authority if large spillage
13. DISPOSAL CONSIDERATIONS General Information
Dispose of as hazardous waste in compliance with local and national regulations.
Contaminated packaging 14. TRANSPORT INFORMATION UN-No 3082 Packing group III Hazard ID 90 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains permethrin and tetramethrin)
UN-No 3082 Packing group III Marine pollutant No EmS F-A S-F Vulcan P RFU IATA-DGR UN-No 3082 Packing group III Sub-risks - packaging 914 15. REGULATORY INFORMATION Symbol(s):
Xn - Harmful; N - Dangerous for the environment
R-phrase(s)
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 - Harmful: may cause lung damage if swallowed.
S-phrase(s)
To avoid risks to man and the environment, comply with the instructions for use. S23 - Do not breathe fumes/vapour/spray. S24 - Avoid contact with the skin. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions/safety data sheets. S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
16. OTHER INFORMATION Text of R phrases
R20/22 - Harmful by inhalation and if swallowed.
mentioned in Section 2
R43 - May cause sensitization by skin contact. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 - Harmful: may cause lung damage if swallowed.
Recommended restrictions Sources of key data used to compile the datasheet
Raw material suppliers Safety Data Sheets.
Replaces
Revision No.: 1. Changes to Section 2, 3, 12, 13, 14,15, 16
Joint Advisory Council and Advisory Board 152 Joint Advisory Council of the Allianz Companies Chairman of the Supervisory Board E.ON AGD R . D R . H E I N R I C H V O N P I E R E RChairman of the Board of Management Linde AGMember of the Board of Management BASF AG P R O F E S S O R D R . H . C . H A N S - O L A F H E N K E LChairman of the Supervisory Board Heraeus Holding GmbHChairman of
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SAFETY DATA SHEET 
Vulcan P RFU