Microsoft word - vcpl msds - me1208 - 9-in-1 technology oil - r2.doc

Material Safety Data Sheet

SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
Product Name/Identifier 9-In-1 Technology Oil
Product Code
Product Use
Company Information
Vance Chemicals Pte Ltd No.24 Gul Lane Singapore 629418 +65 6863 0863 [email protected] Emergency Contact
SECTION 2
HAZARDS INDENTIFICATION

GHS CLASSIFICATION

Environmental
Physical

GHS LABEL:
EU LABEL:
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 1 of 12
Material Safety Data Sheet
Hazard Statements:
Health hazard statements
Hazard class
Hazard category
May be harmful if swallowed
May be harmful in contact with skin
Causes skin irritation
Causes serious eye irritation
Suspected of causing cancer
May cause damage to organ through
Specific target organ toxicity, repeated prolonged or repeated exposure
Precautionary Statements
Prevention:
Prevention precautionary statements
Hazard class
Hazard category
Obtain special instructions before use
Do not handle until all safety precautions
have been read and understood.
Do not breathe
dust/fume/gas/mist/vapour/spray
Wash thoroughly after handling
Specific target organ toxicity, repeated exposure (chapter 3.8) Specific target organ toxicity, Do not eat, drink or smoke when using this
product.
Wear protective gloves/protective
clothing/eye protection/face protection.
Use personal protective equipment as
required.
Response:
Response precautionary statements
Hazard class
Hazard category
IF ON SKIN: Wash with plenty of soap and
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 2 of 12
Material Safety Data Sheet
IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF EXPOSED OR CONCERNED: Get medical
advice/attention.
If exposed or if you feel unwell: Call a
POISON CENTER or doctor/physician.
Call a POSION CENTER/doctor/physician if
you feel unwell.
Get medical advice/attention if you feel
Specific treatment (see…on this label)
If skin irritation occurs: Get medical
advice/attention.
P337+ P313 If eye irritation persists. Get medical/advice. Eye damage/Irritation (chapter 3.3)
Take off contaminated clothing and wash
before use.
Storage:
Disposal precautionary statements
Hazard class
Hazard category
Store lock up
Disposal:
Disposal precautionary statements
Hazard class
Hazard category
Dispose of content/containers according to
the local/regional/national/international
regulation.
SECTION 3
COMPOSITIONS / INFORMATION ON INGREDIENTS
Chemical Identity
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 3 of 12
Material Safety Data Sheet

SECTION 4
FIRST AID MEASURES
Immediately flush eyes with large amounts of water for at least 15 minutes while Eye contact
holding the eyelids open. If redness, swel ing, pain and blister occur, transport to the nearest medical facility for additional treatment. Remove contaminated clothing. Flush exposed area with large amount of water for at Skin contact
least 15 minutes fol owed by washing with soap. If redness, swel ing, pain and blister occur, transport to the nearest medical facility for additional treatment. Inhalation
Remove to open area for fresh air. If rapid recovery does not occur, transport to the nearest medical facility for additional treatment. If swal owed, do not induce vomiting; transport to nearest medical facility for additional Ingestion
treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspirations. Most Important Symptoms/Effects, Acute and Delayed:
Eye irritation signs and symptoms may include burning sensation, redness, swel ing and/or blurred vision. Skin irritation
signs and symptoms may include a burning sensation, redness, swel ing, and/or blisters. Defatting dermatitis signs and
symptoms may include burning sensation and/or a dried/ cracked appearance. Respiratory irritation signs and symptoms
may include burning sensation of the nose and throat, coughing and difficulty in breathing. If materials enter lungs, signs
and symptoms may include coughing, chocking, wheezing, difficulty in breathing, chest congestion, shortness of breath and
fever.

SECTION 5
FIRE FIGHTING MEASURES
Suitable Extinguishing Media
Non-flammable. Use water spray, carbon dioxide, fog or foam to cool fire exposed surfaces and to protect personnel. Unsuitable Extinguishing Media Do not use water jet.
Specific Hazards Arising from
Hazardous decomposition products. Formation of dangerous gas/vapours in case of the Chemical
decomposition. Gas/vapours may form flammable mixtures in presence of air. Protection for Fire-fighters
Evacuate personnel to safe areas. Intervention only by capable personnel who are trained and aware of the hazards of the product. In the event of fire, wear self-contained breathing apparatus. When intervention in close proximity wear acid resistant over suit. Clean contaminated surface thoroughly.
SECTION 6
ACCIDENTAL RELEASE MEASURES
Personal Precautions and
Refer to protective measures listed in sections 7 and 8. Prevent further leakage or Protective Equipment
spil age if safe to do so. Keep away from open flames, hot surfaces and sources of ignition. Keep away from incompatible products. Isolate the area. Cover the spreading Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 4 of 12
Material Safety Data Sheet
liquid with foam in order to slow down the evaporation. Ventilate the area Environmental Precautions
Prevent discharges into the environment (sewers, rivers, soils). Immediately notify the appropriate authorities in case of discharge. Method for Cleaning Up &
If possible, dam large quantities of liquid with sand or earth. Col ect the product with Containment
suitable means. Place everything into a closed, labeled container compatible with the product. Flush with plenty of water. Prevent product from entering drains. Treat recovered material as described in the section "Disposal considerations”. Emergency Procedures
Shut off leaks, if possible without personal risks. Remove al possible ignitions in the surrounding area. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth or other appropriate barriers. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) al equipment. Monitor area with combustible gas indicator.
SECTION 7
HANDLING AND STORAGE
Precautions for Safe Handling: Use proper bonding and grounding (earthing) al equipment. Electrostatic discharge may
cause fire. Prevent smal spil s and leakage to avoid slip hazard. Avoid contact with skin.
Conditions for Safe Storage: Keep container dry. Keep in a cool, wel -ventilated place. Ground al equipment containing
material. Keep container tightly closed. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents. Storage temperature: Ambient Storage/Transport Pressure: Atmospheric
SECTION 8
EXPOSURE CONTROLS/PERSONAL PROTECTION
Component
ACGIH TLV
ACGIH STEL
OSHA STEL
Hydrotreated petroleum distil ate (light) Engineering Controls
Ensure adequate ventilation. Provide appropriate exhaust ventilation at machinery. Refer to protective measures listed in sections 7 and 8. Apply technical measures to comply with the occupational exposure limits.
Personal Protective Equipment (PPE):
Eye Protection
Wear protective goggles for al industrial operations. If risk of splashing, chemical proof goggles/face shield. Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 5 of 12
Material Safety Data Sheet
Skin Protection
Apron/boots of neoprene if risk of splashing. For hand protection, use chemical resistant protective such as Polyvinyl alcohol coated gloves. Respiratory Protection
In the case of hazardous fumes, wear self contained breathing apparatus. Self-contained breathing apparatus in medium confinement/insufficient oxygen/in case of large uncontrol ed emissions/in al circumstances when the mask and cartridge do not give adequate protection Thermal hazards

SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odour Threshold
Melting Point/ Freezing Point (°C)
Initial boiling point and range (°C)
Flash Point (°C) [According to ISO
3679, Closed Cup Testing]
Evaporation Rate
Flammability (solid, gas)
Vapour Pressure
Upper/lower Flammability
(Explosive) Limits:
Vapour Density
Relative Density
Solubility in water
Partition coefficient (N-Octanol/water)
Auto-ignition Temperature (°C)
Decomposition Temperature:
Viscosity (mPa s)
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 6 of 12
Material Safety Data Sheet

SECTION 10
STABILITY AND REACTIVITY
Strong oxidizers, strong caustics, plastics, rubber, nitric acid, water + heat, and chemical y active metals, such as aluminium and magnesium powder, sodium, Reactivity/Incompatible materials
potassium, and lithium. Avoid contact with open flames and electrical arcs. Liquid dichloromethane wil attack some forms of plastics, rubber, and coatings. Chemical Stability
Stable under ordinary conditions of use and storage. Possibility of hazardous reactions
Wil slowly decompose to hydrogen chloride when exposed to light and Hazardous decomposition products
moisture. May produce carbon monoxide, carbon dioxide and phosgene when heated to decomposition. To avoid thermal decomposition, do not overheat. Keep away from direct Conditions to avoid
Strong bases, oxidizing agents, salts of metals, non iron metals, certain plastic Materials to avoid

SECTION 11
TOXICOLOGICAL INFORMATION
Ingredient Name: Hydrotreated petroleum distil ate (light)
Effects on humans:
Eyes contact
- May cause mild, short-lasting discomfort to eyes. Based on test data for structural y similar materials.
Skin contact
- Repeated exposure may cause skin dryness or cracking.
Inhalation
- May be irritating to nose, throat.
Ingestion
- May cause lung damage if swal owed.
Acute toxicity: LD50 Rat (oral) > 15000 mg/kg
LD50Rabbit (dermal) >3,600 mg/kg
LC50Rat, 4 hours (inhalation) >5500 ppm
Skin corrosion/irritation: Minimal y toxic.
Serious eye damage/irritation: Mild discomfort.
Chronic/Other effects
For the product itself:
Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract may
cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects including
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 7 of 12
Material Safety Data Sheet
death. Prolonged and/or repeated skin contact with low viscosity materials may defat the skin resulting in possible irritations and dermatitis. Smal amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema Ingredient Name: Dichloromethane
Effects on humans:
Eyes contact:
- Severe eye irritation, watering and redness. Risk of temporary eye lesions.
Skin contact:
- The product can be absorbed by intact skin. Irritation. In case of prolonged contact: risk of burns. In case of repeated
contact: dry and chapped skin, risk of chronic dermatitis.
Inhalation:
- Slight nose irritation. At high concentrations, feelings of intoxication, restlessness, dizziness, nausea, vomiting,
drowsiness. At high concentrations, risk of narcosis. At high concentrations, risk of chemical pneumonitis, pulmonary (o)
edema. In case of repeated or prolonged exposure: headaches, fatigue and risk of nervous system
Ingestion:
- Breath smel s of chloroform. Severe irritation of the mouth, throat, esophagus and stomach. Nausea, vomiting, abdominal
cramps and diarrhea. Feelings of intoxication, restlessness, dizziness and drowsiness. Risk of loss of consciousness. Risk
of chemical pneumonitis from product inhalation. Risk liver and kidney alterations. Risk of general symptoms.
Acute toxicity: Oral route, LD 50, rat, 1410 - 2524 mg/kg
Dermal route, LD 50, rat, > 2000 mg/kg
Inhalation, LC 50, 6 h, rat, 52 mg/L
Skin corrosion/irritation: Rabbit, irritant
Serious eye damage/irritation: Rabbit, irritant
Germ cell mutagenicity: Dichloromethane has been evaluated for its potential to induce genotoxic effect in vitro and in
vivo systems with mixed results. Based on this evidence, Dichloromethane exposure may be considered to be a weak
mutagen in mammalian systems.
Carcinogenicity: Anticipated carcinogen, IARC category 2B. Dichloromethane is carcinogenic in experimental animals at a
relatively high dose, by route(s) of administration, at site(s), of histological type(s), or by mechanism(s) that are not
considered relevant to worker exposure.
Reproductive toxicity: No information was found in the secondary sources searched to indicate that Dichloromethane is a
developmental/reproductive toxicant in humans. No significant developmental effects were observed in female rats and
mice exposed to 1250 ppm during gestation. A similar result was observed in rats exposed to 4500 ppm before and during
gestation. A two-generation inhalation study showed no adverse reproductive effects in rats exposed to as much as 1500
ppm for 14 weeks.
Specific target organ toxicity: Oral route, after repeated exposure, Target organ: liver, >= 200 mg/kg. Inhalation, after
prolonged exposure, mouse, Target organ: liver / lungs, carcinogenic effect.
Inhalation, after repeated exposure, various species, Target organ: liver / kidney / lungs / central nervous system, >=
1.000ppm.
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 8 of 12
Material Safety Data Sheet

SECTION 12
ECOLOGICAL INFORMATION
Toxicity
Fishes, various species, LC 50, 96 h, 388 mg/l Crustaceans, Daphnia magna, EC 50, 48 h, from 1468 mg/l This product does not persist in the atmosphere. It is natural y degraded to hydrogen chloride and carbon dioxide. Persistence/Degradability
Atmospheric lifetime is approximately 6 months. The product is slowly biodegradable in water. The product is slowly biodegradable in soil. Bioconcentration: Fishes, Cyprinus carpio, BCF from 6,4 - 40 , 42day(s) Bio accumulative
Conditions: test concentration: 0.025 ppm Potential
Bioconcentration: log Po/w from 1.25 – 1.3 Conditions: measured value Mobility in soil
Significant evaporation and percolation.
SECTION 13
DISPOSAL CONSIDERATIONS
Local legislation Dispose in compliance with local/federal and national regulations. It is recommended to contact the producer for recycling/recovery. Or send the product to an authorized hazardous waste incinerator. The incinerator must be equipped with a system for the neutralization or recovery of HCl. Container Disposal To avoid treatments, as far as possible, use dedicated containers. If not, rinse the empty containers with a low volatility hydrocarbon and treat the effluent in the same way as waste. Containers that cannot be cleaned must be treated as waste.
SECTION 14
TRANSPORT INFORMATION

Land (ADR)
UN number
Subsidiary risk
Packing Group
Proper shipping name
Toxic liquid, organic, N.O.S (Dichloromethane) Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 9 of 12
Material Safety Data Sheet
Sea (IMDG)
UN number
Subsidiary risk
Packing Group
Proper shipping name
Toxic liquid, organic, N.O.S (Dichloromethane) Marine pollutant

Sea (Annex II of MARPOL 73/78 and the IBC Code)
Pollution category
Ship type
Product name

Air (IATA)
UN number
Subsidiary risk
Packing Group
Proper shipping name
Toxic liquid, organic, N.O.S (Dichloromethane)
Special precautions:
Before transportation, make sure the containers are tightly sealed and that there are no liquid or gas leaks. When transporting containers, be sure that they are tightly fastened. An appropriate buffer material should be placed between them to prevent them from bumping each other and being damaged during transport.
SECTION 15
REGULATORY INFORMATION

EU Information
Risk Phrase:
Limited evidence of a carcinogenic effect Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 10 of 12
Material Safety Data Sheet
Harmful: may cause lung damage if swal owed Repeated exposure may cause skin dryness or cracking
Safety Phrase:
Wear suitable protective clothing and gloves If swal owed, do not induce vomiting: seek medical advice immediately and show this container or
USA Information
Comprehensive Environmental Response and Liability Act of 1980 (CERCLA)

Superfund Amendments and Reauthorization Act (SARA) Title III Information:
SARA Section 311/312 (40 CFR 370) Hazard Categories:

This product contains the following toxic chemical(s) subject to reporting requirements of SARA Section 313
(40 CFR 372): Dichloromethane

Canada Information
WHMIS classification:
Dichloromethane
- D1B Toxic material causing immediate and serious toxic effects
D2A Very toxic material causing other toxic effects carcinogenicity: IARC group 2B D2B Toxic material causing other toxic effects eye irritation in animals; skin irritation in animals
SECTION 16
OTHER INFORMATION

Department issuing date sheet: Vance Chemicals Quality Control and Laboratory
Original Issue date: 1st January 2010
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 11 of 12
Material Safety Data Sheet
Issue date: N.A
Revision date: 7th March 2011

This product is intended for use by skil ed individuals at their own risk. The information, data and recommendations set
forth herein are presented in good faith and are believed to be correct as of the date hereof. The company /
manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The information is provided upon the condition that the persons receiving wil
make their own determination as to its suitability for their purposes prior to use. Any use of the Information must be
determined by the user to be in accordance with applicable Federal, state and local laws and regulations. In no event
wil the company / manufacturer be responsible for damages of any nature whatsoever resulting from the use or
reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE
INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
Mr McKenic – 9-in-1 Technology Oil (MSDS) – R2 Page 12 of 12

Source: http://anc.vn/media/VCPL%20MSDS%20-%20ME1208%20-%209-in-1%20Technology%20Oil%20-%20R2.pdf